Abstract:

We show that the non-Markovian quantum dynamics of a system comprised of a subspace Q coupled to a much larger subspace P can be described by a set of Effective Modes Differential Equations (EMDE).  The computational efficiency of the method is demonstrated by investigating the 24-mode decay dynamics and laser control of the radiationless transitions from the second to the first singlet electronic excited state of the pyrazine molecule.

(PLEASE NOTE NON-STANDARD LOCATION)