The
x-ray free electron laser is shaping up to be a revolutionary new tool
for advancing our understanding of the dynamics of matter at the level
of electrons and atoms. Their utility stems from extremely bright
x-ray beams comprising a large number of photons concentrated in
femtosecond pulses with a high-degree transverse coherence and
relatively low repetition-rate. A challenge for scientists is to
devise experiments that make effective use of these unique properties,
in an environment characterized by large shot-to-shot fluctuations and
potential for x-ray induced damage. This may seem like precisely the
wrong source for high-resolution spectroscopy of elementary excitations
in solids. In this colloquium, I will make a case for femtosecond x-ray
scattering as a powerful new tool for studying lattice dynamics,
particularly out of equilibrium. I will draw on two recent examples
from my group where we perform high-resolution inelastic x-ray
scattering in the time-domain using a femtosecond optical laser to
prepare broadband two-phonon coherences in the sample. In the first
experiment, we extract the transverse acoustic phonon dispersion in the
prototypical semiconductor germanium with sub-meV resolution--- without
the use of an analyzer. In the second experiment, we investigate the
strongly anharmonic lattice dynamics in PbTe and present evidence
for strong photo-induced mode-coupling spanning the Brillouin zone.